Application of a mesoporous nanomaterial based on basic ionic liquid anchored to silica as a highly effective catalyst for the production of 2-amino-4H-chromenes

Authors

  • Abdolkarim Zare Department of Chemistry, Payame Noor University, PO Box 19395-3697 Tehran, Iran.
  • Alireza Kohzadian Department of Chemistry, Payame Noor University, PO Box 19395-3697 Tehran, Iran.
  • Zahra Abshirini Department of Chemistry, Payame Noor University, PO Box 19395-3697 Tehran, Iran.
  • Zahra Paryav Department of Chemistry, Payame Noor University, PO Box 19395-3697 Tehran, Iran.
Abstract:

This research describes application of a mesoporous nanostructured material based on basic ionic liquid anchored to silica, i.e. nano-2-(dimethylamino)-N-(silica-n-propyl)-N,N-dimethylethanaminium chloride {nano-[DMSPDE][Cl]}, as a highly effective and heterogeneous nanocatalyst for the production of 2-amino-4H-chromenes. The one-pot multi-component reaction of aromatic aldehydes with malononitrile and 1-naphthol in the presence of nano-[DMSPDE][Cl] under solvent-free conditions affords the title compounds with high yields in short times.

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Journal title

volume 9  issue 3

pages  251- 257

publication date 2019-09-01

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